Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os)

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New developments in the synthesis, crystal and molecular structure, spectroscopy and kinetic properties of the [M(CN)5L]n- ions (MH11,111 = Fe, Ru, Os; L = H2O, NH3, amines, CN-, N-heterocyclic ligands, etc.), performed over the last decade, are reviewed. The properties of dinuclear complexes contai...

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Autor principal: Baraldo, L.M
Otros Autores: Forlano, P., Parise, A.R, Slep, L.D, Olabe, J.A
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2001
Acceso en línea:Registro en Scopus
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100 1 |a Baraldo, L.M. 
245 1 0 |a Advances in the coordination chemistry of [M(CN)5L]n- ions (M = Fe, Ru, Os) 
260 |c 2001 
270 1 0 |m Olabe, J.A.; Departamento de Quimica Inorganica, Fac. de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, C1428EHA Buenos Aires, Argentina; email: olabe@ql.fcen.uba.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a New developments in the synthesis, crystal and molecular structure, spectroscopy and kinetic properties of the [M(CN)5L]n- ions (MH11,111 = Fe, Ru, Os; L = H2O, NH3, amines, CN-, N-heterocyclic ligands, etc.), performed over the last decade, are reviewed. The properties of dinuclear complexes containing pentacyano-fragments bridged by pyrazine, cyanide or other bridging ligands, are also considered, with emphasis on mixed-valent systems. The influence of the solvent and other medium effects on the electronic structure, as well as on the modification of the reactivity of L upon coordination is addressed particularly. Some catalytic processes relevant to bioinorganic chemistry are discussed, involving either ligand oxidation (hydrazine, thiolates) or reduction (nitrosyl). © 2001 Elsevier Science B.V. All rights reserved.  |l eng 
536 |a Detalles de la financiación: Universidad de Buenos Aires 
536 |a Detalles de la financiación: Fundación Antorchas 
536 |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires, TW 62 
536 |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, 01703 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, 4653 
536 |a Detalles de la financiación: The authors gratefully acknowledge main financial support from the University of Buenos Aires, ANPCyT (grant 01703), CONICET (grant 4653), UBACyT (grant TW 62), as well as a complementary aid from Fundación Antorchas. L.M.B and J.A.O are members of the research staff of CONICET. 
593 |a Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, C1428EHA Buenos Aires, Argentina 
690 1 0 |a CYANIDE-BRIDGED SYSTEMS 
690 1 0 |a MIXED-VALENT COMPLEXES 
690 1 0 |a PENTACYANO-L-METALATES 
690 1 0 |a REACTIONS OF COORDINATED LIGANDS 
690 1 0 |a COORDINATION COMPOUND 
690 1 0 |a CYANIDE 
690 1 0 |a HYDRAZINE 
690 1 0 |a IRON DERIVATIVE 
690 1 0 |a LIGAND 
690 1 0 |a OSMIUM DERIVATIVE 
690 1 0 |a PYRAZINE 
690 1 0 |a RUTHENIUM DERIVATIVE 
690 1 0 |a CATALYSIS 
690 1 0 |a CHEMICAL STRUCTURE 
690 1 0 |a COMPLEX FORMATION 
690 1 0 |a CRYSTALLOGRAPHY 
690 1 0 |a ELECTRON TRANSPORT 
690 1 0 |a OXIDATION 
690 1 0 |a REVIEW 
690 1 0 |a SPECTROSCOPY 
690 1 0 |a SYNTHESIS 
700 1 |a Forlano, P. 
700 1 |a Parise, A.R. 
700 1 |a Slep, L.D. 
700 1 |a Olabe, J.A. 
773 0 |d 2001  |g v. 219-221  |h pp. 881-921  |p Coord. Chem. Rev.  |x 00108545  |w (AR-BaUEN)CENRE-4327  |t Coordination Chemistry Reviews 
856 4 1 |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0034775008&doi=10.1016%2fS0010-8545%2801%2900383-6&partnerID=40&md5=b2c6d37bdc54da12ba686b7ecee6e0b6  |y Registro en Scopus 
856 4 0 |u https://doi.org/10.1016/S0010-8545(01)00383-6  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_00108545_v219-221_n_p881_Baraldo  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00108545_v219-221_n_p881_Baraldo  |y Registro en la Biblioteca Digital 
961 |a paper_00108545_v219-221_n_p881_Baraldo  |b paper  |c PE 
962 |a info:eu-repo/semantics/article  |a info:ar-repo/semantics/artículo  |b info:eu-repo/semantics/publishedVersion 
999 |c 62893 

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