Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide
The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give...
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| Formato: | Capítulo de libro |
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2002
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 03731caa a22005777a 4500 | ||
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| 001 | PAPER-5354 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203500.0 | ||
| 008 | 190411s2002 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0038451524 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ORGND | ||
| 100 | 1 | |a Trápani, C. | |
| 245 | 1 | 0 | |a Formation of n-butyldiazoate by reaction of [M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide |
| 260 | |c 2002 | ||
| 270 | 1 | 0 | |m Doctorovich, F.; Depto. de Quím. Inorg., INQUIMAE, Pabellón II, piso 3, C1428EHA Buenos Aires, Argentina; email: doctorovich@qi.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Bowden, W.L., Little, W.F., Meyer, T.J., (1977) J. Am. Chem. Soc., 99, p. 4340 | ||
| 504 | |a Doctorovich, F., Trápani, C., (1999) Tetrahedron Lett., 40, p. 4635 | ||
| 504 | |a Doctorovich, F., Escola, N., Trápani, C., Estrin, D.A., Turjanski, A.G., González Lebrero, M.C., (2000) Organometallics, 19, p. 3810 | ||
| 504 | |a Doctorovich, F., Granara, M., Di Salvo, F., (2001) Transition Met. Chem., 26, p. 505 | ||
| 504 | |a Di Salvo, F., Crespo, A., Escola, N., Estrin, D.A., Doctorovich, F., Tetrahedron, , in press | ||
| 504 | |a note; Aubrecht, K.B., Lucht, B.L., Collum, D.B., (1999) Organometallics, 18, p. 2981 | ||
| 504 | |a Watson, S.C., Eastham, J.F., (1967) J. Organomet. Chew., 9, p. 165 | ||
| 504 | |a note; Thiele, J., (1908) Chem. Ber., 41, p. 2806 | ||
| 504 | |a Baraldo, L.M., Forlano, P., Parise, A.R., Slep, L., Olabe, J.A., (2001) Coord. Chem. Rev., 219-221, p. 881 | ||
| 504 | |a Ho, J., Fishbein, J.C., (1994) J. Am. Chem. Soc., 116, p. 6611 | ||
| 504 | |a Lown, J.W., Chauhan, S.M.S., Koganty, R.R., Sapse, A.-N., (1984) J. Am. Chem. Soc., 106, p. 6401 | ||
| 504 | |a The pKa for n-butyldiazoate is 8.77.12 | ||
| 520 | 3 | |a The reactions of[M(CN)5NO]2- (M = Fe, Ru, Os) with lithium n-butylamide are reported for the first time. Free (E)-n-butyldiazoate was found as the only product arising from the amide. This result and the reinvestigation of the reactions of n-butylamine with [Fe(CN)5NO]2- and [Ru(bpy)2(NO)Cl]2+ give a strong indication that diazoates (and/or diazoic acids) are intermediates in the reactions of amines with these nitrosyl complexes. |l eng | |
| 593 | |a Dept. de Química Inorgánica, Analítica y Química Física/INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, piso 3, C1428EHA Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a NUCLEOPHILIC ATTACKS |
| 690 | 1 | 0 | |a CONCENTRATION (PROCESS) |
| 690 | 1 | 0 | |a FOURIER TRANSFORM INFRARED SPECTROSCOPY |
| 690 | 1 | 0 | |a LITHIUM COMPOUNDS |
| 690 | 1 | 0 | |a MIXTURES |
| 690 | 1 | 0 | |a NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY |
| 690 | 1 | 0 | |a PHASE EQUILIBRIA |
| 690 | 1 | 0 | |a STOICHIOMETRY |
| 690 | 1 | 0 | |a ULTRAVIOLET SPECTROSCOPY |
| 690 | 1 | 0 | |a ORGANOMETALLICS |
| 700 | 1 | |a Escola, N. | |
| 700 | 1 | |a Doctorovich, F. | |
| 773 | 0 | |d 2002 |g v. 21 |h pp. 2021-2023 |k n. 10 |p Organometallics |x 02767333 |w (AR-BaUEN)CENRE-2351 |t Organometallics | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-0038451524&doi=10.1021%2fom011026h&partnerID=40&md5=70cdb8ec281fff46d44104bd6c4fdfd0 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1021/om011026h |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_02767333_v21_n10_p2021_Trapani |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v21_n10_p2021_Trapani |y Registro en la Biblioteca Digital |
| 961 | |a paper_02767333_v21_n10_p2021_Trapani |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 66307 | ||