Alternative synthesis of (24S)-homoethylcastasterone from stigmasterol

24(S)-Homoethylcastasterone belongs to the group of natural products named brassinosteroids. This work reports its synthesis from stigmasterol through a new pathway which involves a reductive opening of a 5β,6β-steroidal epoxide derivative. Key intermediate compound 4a also allows to develop pathway...

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Detalles Bibliográficos
Autor principal: Teme Centurión, Osvaldo Miguel
Publicado: 1998
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03650375_v86_n3-6_p104_TemeCenturion
http://hdl.handle.net/20.500.12110/paper_03650375_v86_n3-6_p104_TemeCenturion
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