Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw*
Methanolysis of acylated carbohydrate derivatives was effectively performed using tertiary amines in the absence of water at room temperature. The reaction was performed with acetylated and benzoylated alditols, aldoses, lactones, orthoesters, glycosides, and disaccharides. ^-methyl-pyrrolidine prov...
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1993
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v12_n1_p13_Moradei http://hdl.handle.net/20.500.12110/paper_07328303_v12_n1_p13_Moradei |
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paper:paper_07328303_v12_n1_p13_Moradei2023-06-08T15:43:55Z Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* Moradei, Oscar Miguel Leit, Silvana Marcela Methanolysis of acylated carbohydrate derivatives was effectively performed using tertiary amines in the absence of water at room temperature. The reaction was performed with acetylated and benzoylated alditols, aldoses, lactones, orthoesters, glycosides, and disaccharides. ^-methyl-pyrrolidine proved to be especially suitable for synthetic purposes and deacylated compounds were obtained in excellent yields. The mild conditions employed and the minimum work-up needed make this method appropriate for the deacylation of labile compounds. © 1993, Taylor & Francis Group, LLC. All rights reserved. Fil:Moradei, O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Leit, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1993 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v12_n1_p13_Moradei http://hdl.handle.net/20.500.12110/paper_07328303_v12_n1_p13_Moradei |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| description |
Methanolysis of acylated carbohydrate derivatives was effectively performed using tertiary amines in the absence of water at room temperature. The reaction was performed with acetylated and benzoylated alditols, aldoses, lactones, orthoesters, glycosides, and disaccharides. ^-methyl-pyrrolidine proved to be especially suitable for synthetic purposes and deacylated compounds were obtained in excellent yields. The mild conditions employed and the minimum work-up needed make this method appropriate for the deacylation of labile compounds. © 1993, Taylor & Francis Group, LLC. All rights reserved. |
| author |
Moradei, Oscar Miguel Leit, Silvana Marcela |
| spellingShingle |
Moradei, Oscar Miguel Leit, Silvana Marcela Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| author_facet |
Moradei, Oscar Miguel Leit, Silvana Marcela |
| author_sort |
Moradei, Oscar Miguel |
| title |
Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| title_short |
Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| title_full |
Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| title_fullStr |
Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| title_full_unstemmed |
Amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| title_sort |
amine-induced deacylation of carbohydrate derivatives under anhydrous conditionsw* |
| publishDate |
1993 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v12_n1_p13_Moradei http://hdl.handle.net/20.500.12110/paper_07328303_v12_n1_p13_Moradei |
| work_keys_str_mv |
AT moradeioscarmiguel amineinduceddeacylationofcarbohydratederivativesunderanhydrousconditionsw AT leitsilvanamarcela amineinduceddeacylationofcarbohydratederivativesunderanhydrousconditionsw |
| _version_ |
1768545234199773184 |