Butylbis(diphenylglyoximato)(pyridine-κN)-cobalt(III)

In the title compound, [Co(C 4 H 9 )(C 14 H 11 N 2 O 2 ) 2 (C 5 H 5 N)], the Co III atom is coordinated by a butyl group, a nitro-gen-bonded pyridine and two N,N′-bidentate diphenyl-glyoximate ligands in a distorted octa-hedral geometry. The crystal structure features two short O - H⋯O bridges betwe...

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Detalles Bibliográficos
Publicado: 2012
Materias:
data-to-parameter ratio = 15.7
mean σ(C-C) = 0.007 Å
R factor = 0.069
single-crystal X-ray study
T = 100 K
wR factor = 0.184
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_16005368_v68_n2_p_Kumar
http://hdl.handle.net/20.500.12110/paper_16005368_v68_n2_p_Kumar
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:In the title compound, [Co(C 4 H 9 )(C 14 H 11 N 2 O 2 ) 2 (C 5 H 5 N)], the Co III atom is coordinated by a butyl group, a nitro-gen-bonded pyridine and two N,N′-bidentate diphenyl-glyoximate ligands in a distorted octa-hedral geometry. The crystal structure features two short O - H⋯O bridges between the two chelating anions, with O⋯O distances less than 2.5 Å.

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