Separation and quantitation of enantiomeric 3,6-anhydrogalactoses by conversion to the corresponding diastereomeric acetylated sec-butyl 3,6-anhydrogalactonates

A method to determine the proportion of both enantiomers of 3,6-anhydrogalactose in a sample has been developed using methyl 3,6-anhydro-α-d-galactoside as a model compound. It involves an oxidative hydrolysis to obtain the corresponding aldonic acids, which are further converted to the acetylated d...

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Detalles Bibliográficos
Autores principales: Errea, M., Ciancia, M., Matulewicz, M., Cerezo, A.
Formato: JOUR
Materias:
3,6-Anhydrogalactonic acids
3,6-Anhydrogalactonic acids, sec-butyl esters
3,6-Anhydrogalactose
3,6-Anhydrogalactose, enantiomers
Seaweed polysaccharides
galactose
polysaccharide
article
carbohydrate synthesis
diastereoisomer
enantiomer
hydrolysis
oxidation
priority journal
seaweed
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v311_n4_p235_Errea
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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