Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the c...
| Autores principales: | , , , |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes |
| Aporte de: |
| Sumario: | The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the carbon chain, whereas, for those having the xylo, ribo, and gluco configurations, the values of the coupling constants indicate that a bent conformation is favored. © 1975. |
|---|