Liquid-gas AsF3 IR frequency shifts

The ir spectrum of AsF3 has been obtained in the gas and liquid phases and the intensities of the fundamental bands in the gas have been measured. It is confirmed that a plot of the relative Δv/v liquid-gas shifts vs. δμ/δSj is linear and consequently the following values for δμ/δSj have been chosen...

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Detalles Bibliográficos
Autor principal: de Mandirola, O.B.
Formato: JOUR
Lenguaje:English
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00222860_v3_n6_p465_deMandirola
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Sumario:The ir spectrum of AsF3 has been obtained in the gas and liquid phases and the intensities of the fundamental bands in the gas have been measured. It is confirmed that a plot of the relative Δv/v liquid-gas shifts vs. δμ/δSj is linear and consequently the following values for δμ/δSj have been chosen: +0.52 and +0.91 D Å-1 for v1 and v3, and -0.372 and -0.008 D for v2 and v4. © 1969.