Liquid-gas AsF3 IR frequency shifts
The ir spectrum of AsF3 has been obtained in the gas and liquid phases and the intensities of the fundamental bands in the gas have been measured. It is confirmed that a plot of the relative Δv/v liquid-gas shifts vs. δμ/δSj is linear and consequently the following values for δμ/δSj have been chosen...
| Autor principal: | |
|---|---|
| Formato: | JOUR |
| Lenguaje: | English |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00222860_v3_n6_p465_deMandirola |
| Aporte de: |
| Sumario: | The ir spectrum of AsF3 has been obtained in the gas and liquid phases and the intensities of the fundamental bands in the gas have been measured. It is confirmed that a plot of the relative Δv/v liquid-gas shifts vs. δμ/δSj is linear and consequently the following values for δμ/δSj have been chosen: +0.52 and +0.91 D Å-1 for v1 and v3, and -0.372 and -0.008 D for v2 and v4. © 1969. |
|---|