Anomalous Horner-Wadsworth-Emmons reactions on 3,4-enuloses

Pyranosic enuloses were subjected to Horner-Wadsworth-Emmons (HWE) conditions using the enolate of dimethyl(methoxycarbonyl)methyl phosphonate and its ethyl analogue. 3-O-Phosphorylation of the products as well as an unusual stereospecificity were observed. A mechanism involving a phosphonate-phosph...

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Detalles Bibliográficos
Autores principales:	Moradei, O.M., Du Mortier, C.M., Cirelli, A.F.
Formato:	JOUR
Materias:	sugar phosphate article carbohydrate synthesis drug synthesis in vitro study methodology nuclear magnetic resonance spectroscopy priority journal reaction analysis stereochemistry
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00404020_v53_n22_p7397_Moradei
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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