Harmonic model of molecular rearrangement collisions

A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical...

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Detalles Bibliográficos
Autor principal: Blum, L.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_03693554_v45_n1_p32_Blum
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spelling todo:paper_03693554_v45_n1_p32_Blum2023-10-03T15:28:28Z Harmonic model of molecular rearrangement collisions Blum, L. A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical example is calculated. The results show that the sometimes very low steric factors in chemical kinetics may be explained by this model. © 1966 Società Italiana di Fisica. Fil:Blum, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical example is calculated. The results show that the sometimes very low steric factors in chemical kinetics may be explained by this model. © 1966 Società Italiana di Fisica.
format JOUR
author Blum, L.
spellingShingle Blum, L.
Harmonic model of molecular rearrangement collisions
author_facet Blum, L.
author_sort Blum, L.
title Harmonic model of molecular rearrangement collisions
title_short Harmonic model of molecular rearrangement collisions
title_full Harmonic model of molecular rearrangement collisions
title_fullStr Harmonic model of molecular rearrangement collisions
title_full_unstemmed Harmonic model of molecular rearrangement collisions
title_sort harmonic model of molecular rearrangement collisions
url http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
work_keys_str_mv AT bluml harmonicmodelofmolecularrearrangementcollisions
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