A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8
Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500-250 cm-1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based...
Autor principal: | |
---|---|
Formato: | JOUR |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_05848539_v47_n6_p799_Perec |
Aporte de: |
Sumario: | Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500-250 cm-1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based on D2d symmetry has been carried out and used to support the vibrational assignments. © 1991. |
---|