A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8
Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500-250 cm-1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based...
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_05848539_v47_n6_p799_Perec |
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| Sumario: | Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500-250 cm-1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based on D2d symmetry has been carried out and used to support the vibrational assignments. © 1991. |
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