Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)

In the title compound, [Co(C 4 H 9 )(C 4 H 7 N 2 O 2 ) 2 (C 5 H 5 N)], which was prepared as a model complex of vitamin B12, the Co III atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl-glyoximate ligands in a distorted octa-hedral geometry. The bis-chelating dimethyl-...

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Detalles Bibliográficos
Autores principales: Kumar, S., Thapa, S.
Formato: JOUR
Materias:
data-to-parameter ratio = 13.3
mean σ(C-C) = 0.006 Å
R factor = 0.042
single-crystal X-ray study
T = 100 K
wR factor = 0.100
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_16005368_v68_n2_pm156_Kumar
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id todo:paper_16005368_v68_n2_pm156_Kumar
record_format dspace
spelling todo:paper_16005368_v68_n2_pm156_Kumar2023-10-03T16:27:46Z Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III) Kumar, S. Thapa, S. data-to-parameter ratio = 13.3 mean σ(C-C) = 0.006 Å R factor = 0.042 single-crystal X-ray study T = 100 K wR factor = 0.100 In the title compound, [Co(C 4 H 9 )(C 4 H 7 N 2 O 2 ) 2 (C 5 H 5 N)], which was prepared as a model complex of vitamin B12, the Co III atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl-glyoximate ligands in a distorted octa-hedral geometry. The bis-chelating dimethyl-glyoximate ligands, which occupy equatorial sites, are linked by strong intra-molecular O - H⋯O hydrogen bonds. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_16005368_v68_n2_pm156_Kumar
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic data-to-parameter ratio = 13.3
mean σ(C-C) = 0.006 Å
R factor = 0.042
single-crystal X-ray study
T = 100 K
wR factor = 0.100
spellingShingle data-to-parameter ratio = 13.3
mean σ(C-C) = 0.006 Å
R factor = 0.042
single-crystal X-ray study
T = 100 K
wR factor = 0.100
Kumar, S.
Thapa, S.
Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
topic_facet data-to-parameter ratio = 13.3
mean σ(C-C) = 0.006 Å
R factor = 0.042
single-crystal X-ray study
T = 100 K
wR factor = 0.100
description In the title compound, [Co(C 4 H 9 )(C 4 H 7 N 2 O 2 ) 2 (C 5 H 5 N)], which was prepared as a model complex of vitamin B12, the Co III atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethyl-glyoximate ligands in a distorted octa-hedral geometry. The bis-chelating dimethyl-glyoximate ligands, which occupy equatorial sites, are linked by strong intra-molecular O - H⋯O hydrogen bonds.
format JOUR
author Kumar, S.
Thapa, S.
author_facet Kumar, S.
Thapa, S.
author_sort Kumar, S.
title Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
title_short Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
title_full Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
title_fullStr Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
title_full_unstemmed Butylbis(dimethylglyoximato-κ 2 N,N′)(pyridine- κN)cobalt(III)
title_sort butylbis(dimethylglyoximato-κ 2 n,n′)(pyridine- κn)cobalt(iii)
url http://hdl.handle.net/20.500.12110/paper_16005368_v68_n2_pm156_Kumar
work_keys_str_mv AT kumars butylbisdimethylglyoximatok2nnpyridinekncobaltiii
AT thapas butylbisdimethylglyoximatok2nnpyridinekncobaltiii
_version_ 1807315824922329088

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