Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization
Two lanthanide(III) complexes with l-glutamate ligands [{Ln2(l-Glu)2(H2O)8} · 4(ClO4) · 2.5H2O]n (Ln = Gd (1), Eu (2)) have been prepared and characterized by single-crystal X-ray diffraction. The compounds are isomorphous with infinite cationic 2D layers stacked together by secondary bonds. The bui...
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2006
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100 | 1 | |a Barja, B. | |
245 | 1 | 0 | |a Gadolinium(III) and europium(III) l-glutamates: Synthesis and characterization |
260 | |c 2006 | ||
270 | 1 | 0 | |m Calvo, R.; Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina; email: calvo@fbcb.unl.edu.ar |
504 | |a Tsuchiya, D., Kunishima, N., Kamiya, N., Jingami, H., Morikawa, K., (2002) Proc. Natl. Acad. Sci. USA, 99 (5), p. 2660 | ||
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504 | |a Parker, D., Dickins, R.S., Puschmann, H., Crossland, C., Howard, S.A.K., (2002) Chem. Rev., 102, p. 1977 | ||
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504 | |a Dauter, Z., Dauter, M., Rajashankar, K.R., (2000) Acta Crystallogr., Sect. D, 56, p. 232 | ||
504 | |a Nagem, R.A.P., Dauter, Z., Polikarpov, I., (2001) Acta Crystallogr., Sect. D, 57, p. 996 | ||
504 | |a Bünzli, J.-C.G., (1989) Lanthanide Probes in Life, Chemical and Earth Science, , Bünzli J.-C.G., and Chopin G.R. (Eds), Elsevier, Amsterdam | ||
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504 | |a Allen, F.H., (2002) Acta Crystallogr., Sect. B, 58, p. 380 | ||
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504 | |a Roeges, N.P.J., (1994) A Guide to the Complete Interpretation of the Infrared Spectra of Organic Structures, , Wiley, Chichester, England | ||
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504 | |a Baggio, R., Calvo, R., Garland, M.T., Peña, O., Perec, M., Rizzi, A., (2005) Inorg. Chem., 44, p. 8979 | ||
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506 | |2 openaire |e Política editorial | ||
520 | 3 | |a Two lanthanide(III) complexes with l-glutamate ligands [{Ln2(l-Glu)2(H2O)8} · 4(ClO4) · 2.5H2O]n (Ln = Gd (1), Eu (2)) have been prepared and characterized by single-crystal X-ray diffraction. The compounds are isomorphous with infinite cationic 2D layers stacked together by secondary bonds. The building blocks are slightly different non-centrosymmetric dinuclear units placed in alternating layers, the resulting structures thus containing four non-equivalent Ln metal sites. The dinuclear units contain a fourfold bridge, two in the η1:η1:μ2 and two in the η2:η1:μ2 modes, from two α- and two γ-carboxylates of four different l-Glu residues, respectively. © 2006 Elsevier B.V. All rights reserved. |l eng | |
536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 06-13782, CONICYT-FONDAP 11980002 | ||
536 | |a Detalles de la financiación: We thank the Spanish Research Council (CSIC) for providing some of us with free-of-charge licenses to the CSD system. The work at INQUIMAE has been supported by PIP 02568 and PIP 5274. The work at UNL was supported by grants CAI+D-UNL, PIP 5274 and ANPCyT PICT 06-13782 and the work in Chile by Project CONICYT-FONDAP 11980002. M.P. and R.C. are members of CONICET. Appendix A | ||
593 | |a Departamento de Química Inorgánica Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, INQUIMAE, Ciudad Universitaria, Pabellon II, 1428 Buenos Aires, Argentina | ||
593 | |a Departamento de Física, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, 1650 San Martín, Buenos Aires, Argentina | ||
593 | |a Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and INTEC (CONICET-UNL), Güemes 3450, 3000 Santa Fe, Argentina | ||
593 | |a Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Av. Blanco Encalada 2008, Casilla 483, Santiago, Chile | ||
690 | 1 | 0 | |a EUROPIUM |
690 | 1 | 0 | |a GADOLINIUM |
690 | 1 | 0 | |a L-GLUTAMIC ACID |
690 | 1 | 0 | |a SPECTROSCOPY |
690 | 1 | 0 | |a X-RAY STRUCTURES |
700 | 1 | |a Calvo, Rafael A. | |
700 | 1 | |a Calvo, R. | |
700 | 1 | |a Garland, M.T. | |
700 | 1 | |a Perec, M. | |
700 | 1 | |a Rizzi, A. | |
773 | 0 | |d 2006 |g v. 359 |h pp. 3921-3926 |k n. 12 |p Inorg. Chim. Acta |x 00201693 |w (AR-BaUEN)CENRE-31 |t Inorganica Chimica Acta | |
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