Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the activation treatments

The effect of the Ni(II)-Mg(II)-Al(III) layered double hydroxide (LDH) activation conditions over the surface and bulk composition and the catalytic performance in ethanol steam reforming (ESR) is studied. Ternary oxides were prepared by thermal decomposition of LDHs synthesized using the homogeneou...

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Detalles Bibliográficos
Autor principal: Romero, A.
Otros Autores: Jobbágy, M., Laborde, M., Baronetti, G., Amadeo, Norma Elvira
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2010
Acceso en línea:Registro en Scopus
DOI
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Registro en la Biblioteca Digital
Aporte de:Registro referencial: Solicitar el recurso aquí
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100 1 |a Romero, A. 
245 1 0 |a Ni(II)-Mg(II)-Al(III) catalysts for hydrogen production from ethanol steam reforming: Influence of the activation treatments 
260 |c 2010 
270 1 0 |m Amadeo, N.; Laboratorio de Procesos Catalíticos, Departamento de Ingeniería Química, Facultad de Ingeniería Ciudad Universitaria, 1428 Buenos Aires, Argentina; email: norma@di.fcen.uba.ar 
504 |a Comas, J., Mariño, F., Laborde, M., Amadeo, N., (2004) Chem. Eng. J., 98 (1-2), p. 61 
504 |a Mariño, F., Cerrella, E., Duhalde, S., Jobbágy, M., Laborde, M., (1998) Int. J. Hydrogen Energy, 23, p. 1095 
504 |a Cavallaro, S., (2000) Energy Fuels, 14, p. 1195 
504 |a Freni, S., Mondillo, N., Cavallaro, S., Cacciola, G., Parmon, V., Sobyanin, V., (2000) React. Kinet. Catal. Lett., 71 (1), p. 143 
504 |a Llorca, J., Homes, N., Sales, J., Ramírez de la Piscina, P., (2002) J. Catal., 209, p. 306 
504 |a Mariño, F., Baronetti, G., Jobbágy, M., Laborde, M., (2003) Appl. Catal. A: Gen., 238, p. 41 
504 |a Llorca, J., Ramírez de la Piscina, P., Delmon, J.A., Sales, J., Homes, N., (2003) Appl. Catal. B: Environ., 43, p. 355 
504 |a Cavallaro, S., Chiodo, V., Freni, S., Mondillo, N., Frusteri, F., (2003) Appl. Catal. A: Gen., 249, p. 119 
504 |a Aupretre, F., Descorme, C., Duprez, D., Casanave, D., Uzio, D., (2005) J. Catal., 233, p. 464 
504 |a Akande, A., Idem, R., Delai, A., (2005) Appl. Catal. A: Gen., 287, p. 159 
504 |a Haryanto, A., Fernando, S., Murali, N., Adhikari, S., (2005) Energy Fuels, 19, p. 2098 
504 |a Velu, S., Suzuki, K., Vijayaraj, M., Barman, S., Gopinath, C.S., (2005) Appl. Catal. B, 55, p. 287 
504 |a Mas, V., Dieuzeide, M.L., Jobbágy, M., Baronetti, G., Amadeo, N., Laborde, M., (2008) Catal. Today, 133, p. 319 
504 |a Frusteri, F., Freni, S., Chiodo, V., Spadaro, L., Di Biasi, O., Bonura, G., Cavallaro, S., (2004) Appl. Catal. A: Gen., 270, p. 1 
504 |a Rostrup-Nielsen, J.R., (1974) J. Catal., 33, p. 184 
504 |a Melo, F.V., Morlanés, N., (2008) Catal. Today, 133-135, p. 374 
504 |a Ross, J.R.H., Steel, M.C.F., Zeini-Isfahani, A., (1978) J. Catal., 52, p. 280 
504 |a Dung, N.T., Tichit, D., Chiche, B., Coq, B., (1998) App. Catal. A: Gen., 169, p. 179 
504 |a de, G.J., Soler-Illia, A.A., Jobbágy, M., Candal, R.J., Regazzoni, A.E., Blesa, M.A., (1998) J. Dispers. Sci. Technol., 19, p. 207 
504 |a Jobbágy, M., Blesa, M.A., Regazzoni, A.E., (2007) J. Colloid Interface Sci., 309 (1), p. 72 
504 |a N. Fairley, casaXPS Software, 2.3.13 Version, 2007-12-03; Wagner, C., Naumkin, A., Kraut-Vass, A., Allison, J., Powell, C., Rumble, J., NIST X-Ray Database 20, Version 3.4 (Web version). NIST Standard Reference database 20, , National Institute of Standars and Tecnology, Gaintherburg, USA 
504 |a Rives, V., Ulibarri, M.A., (1999) Coord. Chem. Rev., 181, p. 61 
504 |a de, G.J., Soler-Illia, A.A., Jobbágy, M., Regazzoni, A.E., Blesa, M.A., (1999) Chem. Mater., 11, p. 3140 
504 |a Cavani, F., Trifiró, F., Vaccari, A., (1991) Catal. Today, 11, p. 173 
504 |a Lebedeba, O., Tichit, D., Coq, B., (1999) Appl. Catal. A: Gen., 183, p. 61 
504 |a Jirátová, K., Cuba, P., Kovanda, F., Hilaire, L., Pitchon, V., (2002) Catal. Today, 76, p. 43 
504 |a Gazzano, M., Kagunya, W., Matteuzzi, D., Vaccari, A., (1997) J. Phys. Chem. B, 101 (23), p. 4514 
504 |a Clause, O., Gazzano, M., Trifirò, F., Vaccari, A., Zatorski, L., (1991) Appl. Catal., 73 (2), p. 217 
504 |a Rodriguez, J., Hanson, J., Frenkel, A., Kim, J., Perez, M., (2002) J. Am. Chem. Soc., 124, p. 346 
504 |a Tichit, T., Medina, F., Coq, B., Dutartre, R., (1997) Appl. Catal. A: Gen., 159, p. 241 
504 |a Hoffer, B.W., Dick van Langeveld, A., Janssens, J.P., Bonné, R.L.C., Lok, C.M., Moulijn, J.A., (2000) J. Catal., 192, p. 432 
504 |a Scheffer, B., Molhoek, P., Moulijn, J.A., (1989) Appl. Catal., 46, p. 11 
504 |a Dussault, L., Dupin, J., Guimon, C., Monthioux, M., Latorre, N., Ubieto, T., Romeo, E., Monzón, A., (2007) J. Catal., 251, p. 223 
504 |a Guil-López, R., La Parola, V., Peña, M., Fierro, J.L.G., (2006) Catal. Today, 116, p. 289 
504 |a Rebours, B., d'Espinose de la Caillerie, J., Clause, O., (1994) J. Am. Chem. Soc., 116, p. 1707 
504 |a Bellotto, M., Rebours, B., Clause, O., (1996) J. Phys. Chem., 100 (20), p. 8527 
504 |a Bellotto, M., Rebours, B., Clause, O., (1996) J. Phys. Chem., 100 (20), p. 8535 
504 |a Sileo, E., Jobbágy, M., Paiva-Santos, C., Regazzoni, A., (2005) J. Phys. Chem. B, 109, p. 10137 
504 |a Basile, F., Basini, L., D'Amore, M., Fornasari, G., Guarinoni, A., Matteuzzi, D., Del Piero, G., Vaccari, A., (1998) J. Catal., 173, p. 247 
504 |a Clause, O., Rebours, B., Merlen, E., Trifirò, F., Vaccari, A., (1992) J. Catal., 133, p. 231 
506 |2 openaire  |e Política editorial 
520 3 |a The effect of the Ni(II)-Mg(II)-Al(III) layered double hydroxide (LDH) activation conditions over the surface and bulk composition and the catalytic performance in ethanol steam reforming (ESR) is studied. Ternary oxides were prepared by thermal decomposition of LDHs synthesized using the homogeneous precipitation method with urea. Catalyst precursor is submitted to two different activation treatments: calcinations at 400, 500, 600 and 700 °C with subsequent reduction at 720 °C, or direct reduction at 720 °C. The samples were characterized by sorptometry, H2 chemisorption, ICP chemical analysis, thermogravimetric analysis, X-ray diffraction, X-ray photoelectronic spectroscopy and temperature programming reduction. The catalysts obtained by calcination at 600 °C and then reduction at 720 °C and those directly reduced at 720 °C showed the better performance in ESR. The precursor submitted to a proper thermal treatment develops, through a decoration-demixing process, a Ni(II)-poor spinel-type shell onto NiO domains.  |l eng 
536 |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas, PIP 5215 
536 |a Detalles de la financiación: To ANPCyT, CONICET and UBA, for the economic support. Also, thanks are given to ANPCyT for Grant PME 8-2003 to finance the purchase of the UHV Multi Analysis System. MJ also acknowledge CONICET for the PIP 5215 project financial support. 
593 |a Laboratorio de Procesos Catalíticos, Departamento de Ingeniería Química, Facultad de Ingeniería Ciudad Universitaria, 1428 Buenos Aires, Argentina 
593 |a INQUIMAE, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellon II, Ciudad Universitaria, 1428 Buenos Aires, Argentina 
690 1 0 |a BIOETHANOL 
690 1 0 |a HYDROGEN PRODUCTION 
690 1 0 |a LDH 
690 1 0 |a NI CATALYST 
690 1 0 |a REFORMING 
690 1 0 |a ACTIVATION CONDITIONS 
690 1 0 |a ACTIVATION TREATMENT 
690 1 0 |a BULK COMPOSITIONS 
690 1 0 |a CATALYST PRECURSORS 
690 1 0 |a CATALYTIC PERFORMANCE 
690 1 0 |a DEMIXING PROCESS 
690 1 0 |a DIRECT REDUCTION 
690 1 0 |a ETHANOL STEAM REFORMING 
690 1 0 |a HOMOGENEOUS PRECIPITATION METHOD 
690 1 0 |a LAYERED DOUBLE HYDROXIDES 
690 1 0 |a LDH 
690 1 0 |a NI CATALYSTS 
690 1 0 |a PHOTOELECTRONIC SPECTROSCOPY 
690 1 0 |a SPINEL-TYPE 
690 1 0 |a SUBSEQUENT REDUCTION 
690 1 0 |a TEMPERATURE-PROGRAMMING 
690 1 0 |a TERNARY OXIDES 
690 1 0 |a THERMAL DECOMPOSITIONS 
690 1 0 |a THERMAL TREATMENT 
690 1 0 |a BIOETHANOL 
690 1 0 |a CALCINATION 
690 1 0 |a CATALYSIS 
690 1 0 |a CATALYST ACTIVITY 
690 1 0 |a CHEMICAL ANALYSIS 
690 1 0 |a CHEMISORPTION 
690 1 0 |a ELECTROSLAG REMELTING 
690 1 0 |a ETHANOL 
690 1 0 |a GAS PRODUCERS 
690 1 0 |a HEAT TREATMENT 
690 1 0 |a NICKEL 
690 1 0 |a PRECIPITATION (CHEMICAL) 
690 1 0 |a PYROLYSIS 
690 1 0 |a REACTION KINETICS 
690 1 0 |a STEAM ENGINEERING 
690 1 0 |a THERMOGRAVIMETRIC ANALYSIS 
690 1 0 |a UREA 
690 1 0 |a X RAY DIFFRACTION ANALYSIS 
690 1 0 |a HYDROGEN PRODUCTION 
700 1 |a Jobbágy, M. 
700 1 |a Laborde, M. 
700 1 |a Baronetti, G. 
700 1 |a Amadeo, Norma Elvira 
773 0 |d 2010  |g v. 149  |h pp. 407-412  |k n. 3-4  |p Catal Today  |x 09205861  |w (AR-BaUEN)CENRE-4117  |t Catalysis Today 
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