First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB>
The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in...
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| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
2000
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/112677 https://ri.conicet.gov.ar/11336/53263 https://onlinelibrary.wiley.com/doi/abs/10.1002/1097-4555%28200010%2931%3A10%3C881%3A%3AAID-JRS588%3E3.0.CO%3B2-T |
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| Sumario: | The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. |
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