DEMS and in-situ FTIR investigations of C<sub>3</sub> primary alcohols on platinum electrodes in acid solutions : Part II. Allyl alcohol

On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and e...

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Detalles Bibliográficos
Autores principales: Pastor, E., Wasmus, S., Iwasita, T., Arévalo, M. C., González, S., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1993
Materias:
Ciencias Exactas
Química
Mass spectroscopy
Fourier transform IR spectroscope
Allyl alcohol
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/119264
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:On-line mass spectroscopy (DEMS) and in-situ Fourier transform IR spectroscope (FTIRS) have been employed to study the electro-oxidation and the electroreduction products of allyl alcohol on Pt electrodes in acids. The electroreduction products were propanol and a mixture of propylene, propane and ethane. The main oxidation products were CO<sub>2</sub> and acrolein. Results are interpreted and possible mechanisms are suggested with the participation of adsorbates having different chain lengths and structures.

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