Electrical conductance of hydrogen chloride in dimethylsulphoxide at 25°C
The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electro...
Guardado en:
| Autores principales: | , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1970
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/119387 |
| Aporte de: |
| Sumario: | The electrical conductance of hydrogen chloride solutions in DMSO at 25°C has been studied. The limiting molar conductance is 38·7 int mho cm<sub>2</sub> int mho cm<sub>2</sub>/mol. Conductivity data were interpreted with the Fuoss' theory for associated 1-1 type electrolytes. The association constant related to pair formation is 115·7 l/mol. The mechanism of electricl conduction of HCl in DMSO at infinite dilution resembles that of other 1-1 type electrolytes in the same solvent, in which charges are transported by simple entities in a viscous continuum. |
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