Kraftkonstanten des V0₄³⁻-Ions im Zirkon-Gitter

The force constants for the V0₄³⁻-ion present in the different rare earth orthovanadates of the zircon type have been computed using a modified valence force field and recently reported Raman data. It is shown that the V-0 bond strenghtening runs parallel to the unit cell contraction. The Raman spe...

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Detalles Bibliográficos
Autores principales: Escobar, Marta E., Baran, Enrique José
Formato: Articulo
Lenguaje:Alemán
Publicado: 1980
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/120317
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Sumario:The force constants for the V0₄³⁻-ion present in the different rare earth orthovanadates of the zircon type have been computed using a modified valence force field and recently reported Raman data. It is shown that the V-0 bond strenghtening runs parallel to the unit cell contraction. The Raman spectrum of the tetragonal modification of LaV0₄ is reported for the first time.