Kinetics and mechanism of the electrochemical reduction of NO<sub>2</sub>+ in concentrated sulphuric acid

The electrochemical reduction on gold of NO<sub>2</sub>+ dissolved in concentrated H<sub>2</sub>SO<sub>2</sub> has been studied by means of the rotating disk electrode and cyclic voltammetry, over a wide range of experimental conditions. The kinetic parameters are...

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Detalles Bibliográficos
Autores principales: Calandra, Alfredo J., Tamayo, C., Herrera Gallego, J., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1972
Materias:
Ciencias Exactas
Química
Electrochemical reduction
Kinetics
Gold
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/121721
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:The electrochemical reduction on gold of NO<sub>2</sub>+ dissolved in concentrated H<sub>2</sub>SO<sub>2</sub> has been studied by means of the rotating disk electrode and cyclic voltammetry, over a wide range of experimental conditions. The kinetic parameters are interpreted in terms of the following reaction mechanism, [fórmula]

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