Spectroscopic investigations of C<sub>3</sub>-primary alcohols on platinum electrodes in acid solutions : Part III. Propargyl alcohol

Electro-oxidation and electroreduction of propargyl alcohol (PA) on Pt electrodes in acid solutions was studied using differential electrochemical mass spectrometry and in-situ Fourier transform IR spectroscopy. The main electro-oxidation product is CO<sub>2</sub>. Only very small amount...

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Guardado en:
Detalles Bibliográficos
Autores principales: Pastor, E., Wasmus, S., Iwasita, T., Arévalo, M. C., González, S., Arvia, Alejandro Jorge
Formato: Articulo
Lenguaje:Inglés
Publicado: 1994
Materias:
Ciencias Exactas
Química
propargyl alcohol
platinum electrodes
spectrometry
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/126525
https://www.sciencedirect.com/science/article/abs/pii/002207289303250S
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
Descripción
Sumario:Electro-oxidation and electroreduction of propargyl alcohol (PA) on Pt electrodes in acid solutions was studied using differential electrochemical mass spectrometry and in-situ Fourier transform IR spectroscopy. The main electro-oxidation product is CO<sub>2</sub>. Only very small amounts of propargyl aldehyde are detected at high potentials. Electroreduction of PA yields mainly propane, propylene, propanol, allyl alcohol and small amounts of propyne and ethane. Hydrogenation of the strongly adsorbed residues of PA produces hydrocarbons but not alcohols.

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