Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)
The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) A, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved...
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| Autores principales: | , , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
| Publicado: |
1998
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| Materias: | |
| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/140177 |
| Aporte de: |
| Sumario: | The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) A, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved employing 2902 independent reflections with I>2σ(I) by direct and Fourier methods and refined by a full-matrix least-squares fit to R; 1=0.049. Infrared and Raman spectra of the solid compound and the electronic absorption spectra of its acetonitrilic and ethanolic solutions were recorded and are briefly discussed. |
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