Vibrational properties of tellurium tetrachloride

On the basis of the most recently reported spectroscopic data on vibrational modes in TeCl<SUB>4</SUB> and structural parameters of TeCl<SUB>4</SUB>, an estimation of its main force constants complemented with the calculation of mean amplitudes of vibration in a wide temperat...

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Detalles Bibliográficos
Autor principal: Barán, Enrique José
Formato: Articulo
Lenguaje:Inglés
Publicado: 2005
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Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/83129
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Sumario:On the basis of the most recently reported spectroscopic data on vibrational modes in TeCl<SUB>4</SUB> and structural parameters of TeCl<SUB>4</SUB>, an estimation of its main force constants complemented with the calculation of mean amplitudes of vibration in a wide temperature range have been performed. Also thermodynamic functions for the ideal gaseous state of the molecule calculated, using the statistical mechanics approach.