Conformational properties of ethyl- and 2,2,2-trifluoroethyl thionitrites, (CX3CH2SNO, X = H and F)

The simple 2,2,2-trifluoroethyl thionitrite molecule, CF3CH2SNO, has been prepared in good yield for the first time using CF3CH2SH and NOCl in slight excess. The vapor pressure of the red-brown compound CF3CH2SNO follows, in the temperature range between 226 and 268 K, the equation log p = 12.0-3881...

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Detalles Bibliográficos
Autores principales:	Cánneva, Antonela, Della Védova, Carlos Omar, Mitzel, Norbert W., Erben, Mauricio Federico
Formato:	Articulo Preprint
Lenguaje:	Inglés
Publicado:	2015
Materias:	Química S-nitrosothiol Conformational analysis IR spectroscopy Vibrational properties Molecular structure
Acceso en línea:	http://sedici.unlp.edu.ar/handle/10915/98562 https://ri.conicet.gov.ar/11336/93253 http://pubs.acs.org/doi/abs/10.1021/jp507406w
Aporte de:	SEDICI (UNLP) de Universidad Nacional de La Plata

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