N-Butylpyridinium undecachlorocarbadodecaborate and comparison with similar compounds
The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinate...
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| Autores principales: | , , , , |
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| Formato: | Artículo publishedVersion |
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2011
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| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_01082701_v67_n10_po417_Suarez https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_01082701_v67_n10_po417_Suarez_oai |
| Aporte de: |
| Sumario: | The title compound, C 9H 14N +· CHB 11Cl 11 -, was obtained in the course of our continuing studies of the low-melting salts of closo- and nido-carborane cage anions with alkyl-pyridinium and dialkyl-imidazolium cations. The title compound is the first example of a pyridinium salt of a perchlorinated carborane anion. The structure consists of one N-butyl-pyridinium cation counterbalanced by one perchlorinated carborane cage anion per asymmetric unit. By changing the counter-ion, different packings are observed, and to try to understand this the new structure is compared with five similar compounds. © 2011 International Union of Crystallography. |
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