Synthesis of D-homo analogs of neurosteroids

17(13→18)-Abeo and D-homo analogs of the natural neurosteroid 3α-hydroxy-5αH-pregnan-20-one were prepared by anionic or radical (mercury (II) hydride mediated) rearrangements of steroidal cyclopropylketones respectively.

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Detalles Bibliográficos
Autores principales: Di Chenna, P., Ghini, A.A., Burton, G.
Formato: Artículo publishedVersion
Publicado: 2000
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_14203049_v5_n3_p447_DiChenna
https://repositoriouba.sisbi.uba.ar/gsdl/cgi-bin/library.cgi?a=d&c=artiaex&d=paper_14203049_v5_n3_p447_DiChenna_oai
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Sumario:17(13→18)-Abeo and D-homo analogs of the natural neurosteroid 3α-hydroxy-5αH-pregnan-20-one were prepared by anionic or radical (mercury (II) hydride mediated) rearrangements of steroidal cyclopropylketones respectively.