Reactivity and spectroscopy of the {Ru(DMAP)5} fragment: An {Ru(NH3)5} analogue
Reaction of trans-Ru(DMSO)4Cl2 with DMAP (DMAP = 4-dimethylaminopyridine) yields the yellow [Ru(DMAP)6]2+ cation in good yield. The crystal and molecular structure of [Ru(DMAP) 6]Cl2·6CH3CH2OH was determined by X-ray diffraction methods. The complex crystallizes in the trigonal R3 space group with a...
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2008
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v47_n7_p2416_Rossi http://hdl.handle.net/20.500.12110/paper_00201669_v47_n7_p2416_Rossi |
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