Nitrosyl-centered redox and acid-base interconversions in [Ru(Me 3[9]aneN3)(bpy)(NO)]3,2,1+. The p K a of HNO for its nitroxyl derivative in aqueous solution
This work reports the preparation of a new 6-coordinated nitrosyl compound and its use as a model to explore the redox and acid-base properties of the three redox states of bound nitrosyl (formally NO+, NO •, NO-/HNO) in {RuNO}6,7,8 species. We prepared the octahedral {RuNO}6 complex [Ru(Me3[9] aneN...
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2014
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v53_n2_p981_Codesido http://hdl.handle.net/20.500.12110/paper_00201669_v53_n2_p981_Codesido |
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