Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)

The infrared and Raman spectra (1500-50 cm-1) of the related complexes Zn(S2CNMe2)2(I), [Bu4N][Zn(S2CNMe2)3] (II), Cd(S2CNMe2)2 (III), [Bu4N][Cd(S2CNMe2)3](IV), Cd(S2CNEt2)2(V) and [Bu4N][Cd(S2CNEt2)3] (VI) have been determined. For complexes with coordination number four, metalsulfur stretching fre...

Descripción completa

Detalles Bibliográficos
Publicado: 1989
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v164_n2_p149_Frigerio
http://hdl.handle.net/20.500.12110/paper_00201693_v164_n2_p149_Frigerio
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00201693_v164_n2_p149_Frigerio
record_format dspace
spelling paper:paper_00201693_v164_n2_p149_Frigerio2023-06-08T14:40:47Z Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II) The infrared and Raman spectra (1500-50 cm-1) of the related complexes Zn(S2CNMe2)2(I), [Bu4N][Zn(S2CNMe2)3] (II), Cd(S2CNMe2)2 (III), [Bu4N][Cd(S2CNMe2)3](IV), Cd(S2CNEt2)2(V) and [Bu4N][Cd(S2CNEt2)3] (VI) have been determined. For complexes with coordination number four, metalsulfur stretching frequencies were assigned at 228 cm-1 for I (ZnS), 180 cm-1 for III (CdS) and 208 cm-1 for V (CdS), whereas for complexes with apparent coordination number six they were assigned at 206 cm-1 for II (ZnS) and in the 150-125 cm-1 range for IV and VI (CdS). Thus, expansion of the coordination sphere of the Zn(II) and Cd(II) metal results in a significant shift towards lower energy of the far IR MS vibrations. Other MS sensitive vibrations in the far IR are found in the 385-350 cm-1 range, and are described as mixed ring bending modes with significant MS stretching contribution. © 1989. 1989 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v164_n2_p149_Frigerio http://hdl.handle.net/20.500.12110/paper_00201693_v164_n2_p149_Frigerio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The infrared and Raman spectra (1500-50 cm-1) of the related complexes Zn(S2CNMe2)2(I), [Bu4N][Zn(S2CNMe2)3] (II), Cd(S2CNMe2)2 (III), [Bu4N][Cd(S2CNMe2)3](IV), Cd(S2CNEt2)2(V) and [Bu4N][Cd(S2CNEt2)3] (VI) have been determined. For complexes with coordination number four, metalsulfur stretching frequencies were assigned at 228 cm-1 for I (ZnS), 180 cm-1 for III (CdS) and 208 cm-1 for V (CdS), whereas for complexes with apparent coordination number six they were assigned at 206 cm-1 for II (ZnS) and in the 150-125 cm-1 range for IV and VI (CdS). Thus, expansion of the coordination sphere of the Zn(II) and Cd(II) metal results in a significant shift towards lower energy of the far IR MS vibrations. Other MS sensitive vibrations in the far IR are found in the 385-350 cm-1 range, and are described as mixed ring bending modes with significant MS stretching contribution. © 1989.
title Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
spellingShingle Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
title_short Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
title_full Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
title_fullStr Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
title_full_unstemmed Spectroscopic characterization of anionic tris(N,N-dialkyldithiocarbamate) complexes of zinc(II) and cadmium(II)
title_sort spectroscopic characterization of anionic tris(n,n-dialkyldithiocarbamate) complexes of zinc(ii) and cadmium(ii)
publishDate 1989
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201693_v164_n2_p149_Frigerio
http://hdl.handle.net/20.500.12110/paper_00201693_v164_n2_p149_Frigerio
_version_ 1768545267947143168

Ejemplares similares