R-matrix theory of molecular collisions

The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential ene...

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Detalles Bibliográficos
Publicado: 1966
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00268976_v11_n1_p63_Blum
http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00268976_v11_n1_p63_Blum
record_format dspace
spelling paper:paper_00268976_v11_n1_p63_Blum2023-06-08T14:54:01Z R-matrix theory of molecular collisions The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential energy function the experimental order of magnitude for the steric factor is obtained. When the range of the interacting potential increases, quite narrow Breit-Wigner resonances result. © 1966, Taylor & Francis Group, LLC. All rights reserved. 1966 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00268976_v11_n1_p63_Blum http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The use of Wigner and Eisenbud's R-matrix theory for molecular collisions is discussed. A model of harmonic oscillators is proposed; in this model the activated complex has one negative normal frequency. An example is calculated. The results show that for certain parameters of the potential energy function the experimental order of magnitude for the steric factor is obtained. When the range of the interacting potential increases, quite narrow Breit-Wigner resonances result. © 1966, Taylor & Francis Group, LLC. All rights reserved.
title R-matrix theory of molecular collisions
spellingShingle R-matrix theory of molecular collisions
title_short R-matrix theory of molecular collisions
title_full R-matrix theory of molecular collisions
title_fullStr R-matrix theory of molecular collisions
title_full_unstemmed R-matrix theory of molecular collisions
title_sort r-matrix theory of molecular collisions
publishDate 1966
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00268976_v11_n1_p63_Blum
http://hdl.handle.net/20.500.12110/paper_00268976_v11_n1_p63_Blum
_version_ 1768541880256036864

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