Additive of substituent effects on the chemical shift of the formyl proton in disubstituted benzaldehydes

An additivity relationship of substituent effects on the formyl proton chemical shift has been tested with ten disubstituted benzaldehydes. In most cases it is found that the formyl proton chemical shift, extrapolated to infinite dilution in nitromethane, is in good agreement with that calculated us...

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Autores principales: Castañeda, Hector Osvaldo, Contreras, Rubén Horacio
Publicado: 1980
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00304921_v13_n4_p308_Castaneda
http://hdl.handle.net/20.500.12110/paper_00304921_v13_n4_p308_Castaneda
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Sumario:An additivity relationship of substituent effects on the formyl proton chemical shift has been tested with ten disubstituted benzaldehydes. In most cases it is found that the formyl proton chemical shift, extrapolated to infinite dilution in nitromethane, is in good agreement with that calculated using the additivity relationship. Copyright © 1980 Heyden & Son Ltd.