Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate
The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are b...
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1998
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n5_p591_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v54_n5_p591_Baggio |
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paper:paper_01082701_v54_n5_p591_Baggio2023-06-08T15:10:38Z Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger LaIII cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups, with Eu⋯La separations of 6.95 (1) Å. 1998 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n5_p591_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v54_n5_p591_Baggio |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger LaIII cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups, with Eu⋯La separations of 6.95 (1) Å. |
title |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
spellingShingle |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
title_short |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
title_full |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
title_fullStr |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
title_full_unstemmed |
Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate |
title_sort |
triaquatris(μ-oxydiacetato)europium(iii)-lanthanum(iii) pentahydrate |
publishDate |
1998 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n5_p591_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v54_n5_p591_Baggio |
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1768542357706244096 |