Triaquatris(μ-oxydiacetato)europium(III)-lanthanum(III) pentahydrate
The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are b...
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1998
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v54_n5_p591_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v54_n5_p591_Baggio |
| Aporte de: |
| Sumario: | The new heterobimetallic complex [{LaEu(oda)3(H2O)3.-5H2O} n] (oda = -O2CCH2OCH2CO2 -) has been synthesized and structurally characterized. Three tridentate oda ligands are coordinated to the smaller EuIII cation, while six adjacent outer carboxylate O atoms and three metal-bound water O atoms are bonded to the larger LaIII cation. The structure consists of a three-dimensional network with the metal centers bridged by oda carboxylate groups, with Eu⋯La separations of 6.95 (1) Å. |
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