Synthesis and thermal behaviour of a series of pentacyanoligandferrate(II) complexes
[MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with C...
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1987
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v6_n9_p1757_Sileo http://hdl.handle.net/20.500.12110/paper_02775387_v6_n9_p1757_Sileo |
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| Sumario: | [MmFe(CN)5L·xH2O] (M = Mn, Fe, Co, Ni, Cu; L = pyridine or pyrazine derivative) have been synthesized, and their UV-vis and IR spectral characteristics are reported. Thermolysis of the solids leads to water release, ligand release and/or decomposition, redox interaction between Fe3+ (or Cu2+) with CN- or L, and redox interaction between M2+ (or Cu+) and CN-, yielding elemental metal and metal carbides. © 1987. |
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