Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks

This critical review presents and discusses the recent advances in complex hybrid materials that result from the combination of polymers and mesoporous matrices. Ordered mesoporous materials derived from supramolecular templating present high surface area and tailored pore sizes; pore surfaces can b...

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Detalles Bibliográficos
Autor principal: Soler Illia, Galo Juan de Avila Arturo
Publicado: 2011
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03060012_v40_n2_p1107_SolerIllia
http://hdl.handle.net/20.500.12110/paper_03060012_v40_n2_p1107_SolerIllia
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_03060012_v40_n2_p1107_SolerIllia2023-06-08T15:31:02Z Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks Soler Illia, Galo Juan de Avila Arturo This critical review presents and discusses the recent advances in complex hybrid materials that result from the combination of polymers and mesoporous matrices. Ordered mesoporous materials derived from supramolecular templating present high surface area and tailored pore sizes; pore surfaces can be further modified by organic, organometallic or even biologically active functional groups. This permits the creation of hybrid systems with distinct physical properties or chemical functions located in the framework walls, the pore surface, and the pore interior. Bringing polymeric building blocks into the game opens a new dimension: the possibility to create phase separated regions (functional domains) within the pores that can behave as "reactive pockets" of nanoscale size, with highly controlled chemistry and interactions within restricted volumes. The possibilities of combining "hard" and "soft" building blocks to yield these novel nanocomposite materials with tuneable functional domains ordered in space are potentially infinite. New properties are bound to arise from the synergy of both kinds of components, and their spatial location. The main object of this review is to report on new approaches towards functional polymer-inorganic mesostructured hybrids, as well as to discuss the present challenges in this flourishing research field. Indeed, the powerful concepts resulting from the synergy of sol-gel processing, supramolecular templating and polymer chemistry open new opportunities in the design of advanced functional materials: the tailored production of complex matter displaying spatially-addressed chemistry based on the control of chemical topology. Breakthrough applications are expected in the fields of sustainable energy, environment sensing and remediation, biomaterials, pharmaceutical industry and catalysis, among others (221 references). © 2011 The Royal Society of Chemistry. Fil:Soler-Illia, G.J.A.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03060012_v40_n2_p1107_SolerIllia http://hdl.handle.net/20.500.12110/paper_03060012_v40_n2_p1107_SolerIllia
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description This critical review presents and discusses the recent advances in complex hybrid materials that result from the combination of polymers and mesoporous matrices. Ordered mesoporous materials derived from supramolecular templating present high surface area and tailored pore sizes; pore surfaces can be further modified by organic, organometallic or even biologically active functional groups. This permits the creation of hybrid systems with distinct physical properties or chemical functions located in the framework walls, the pore surface, and the pore interior. Bringing polymeric building blocks into the game opens a new dimension: the possibility to create phase separated regions (functional domains) within the pores that can behave as "reactive pockets" of nanoscale size, with highly controlled chemistry and interactions within restricted volumes. The possibilities of combining "hard" and "soft" building blocks to yield these novel nanocomposite materials with tuneable functional domains ordered in space are potentially infinite. New properties are bound to arise from the synergy of both kinds of components, and their spatial location. The main object of this review is to report on new approaches towards functional polymer-inorganic mesostructured hybrids, as well as to discuss the present challenges in this flourishing research field. Indeed, the powerful concepts resulting from the synergy of sol-gel processing, supramolecular templating and polymer chemistry open new opportunities in the design of advanced functional materials: the tailored production of complex matter displaying spatially-addressed chemistry based on the control of chemical topology. Breakthrough applications are expected in the fields of sustainable energy, environment sensing and remediation, biomaterials, pharmaceutical industry and catalysis, among others (221 references). © 2011 The Royal Society of Chemistry.
author Soler Illia, Galo Juan de Avila Arturo
spellingShingle Soler Illia, Galo Juan de Avila Arturo
Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
author_facet Soler Illia, Galo Juan de Avila Arturo
author_sort Soler Illia, Galo Juan de Avila Arturo
title Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
title_short Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
title_full Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
title_fullStr Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
title_full_unstemmed Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
title_sort multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks
publishDate 2011
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03060012_v40_n2_p1107_SolerIllia
http://hdl.handle.net/20.500.12110/paper_03060012_v40_n2_p1107_SolerIllia
work_keys_str_mv AT solerilliagalojuandeavilaarturo multifunctionalhybridsbycombiningorderedmesoporousmaterialsandmacromolecularbuildingblocks
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