Harmonic model of molecular rearrangement collisions

A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical...

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Detalles Bibliográficos
Autor principal: Blum, Lesser
Publicado: 1966
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03693554_v45_n1_p32_Blum
http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_03693554_v45_n1_p32_Blum
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spelling paper:paper_03693554_v45_n1_p32_Blum2023-06-08T15:36:18Z Harmonic model of molecular rearrangement collisions Blum, Lesser A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical example is calculated. The results show that the sometimes very low steric factors in chemical kinetics may be explained by this model. © 1966 Società Italiana di Fisica. Fil:Blum, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1966 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03693554_v45_n1_p32_Blum http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description A model of harmonic oscillators for molecular rearrangement collisions is proposed. In this model the reaction occurs through the formation of an unstable activated complex. In this complex there is a normal mode with negative frequency. Using the R_matrix theory of Wigner and Eisenbud, a numerical example is calculated. The results show that the sometimes very low steric factors in chemical kinetics may be explained by this model. © 1966 Società Italiana di Fisica.
author Blum, Lesser
spellingShingle Blum, Lesser
Harmonic model of molecular rearrangement collisions
author_facet Blum, Lesser
author_sort Blum, Lesser
title Harmonic model of molecular rearrangement collisions
title_short Harmonic model of molecular rearrangement collisions
title_full Harmonic model of molecular rearrangement collisions
title_fullStr Harmonic model of molecular rearrangement collisions
title_full_unstemmed Harmonic model of molecular rearrangement collisions
title_sort harmonic model of molecular rearrangement collisions
publishDate 1966
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03693554_v45_n1_p32_Blum
http://hdl.handle.net/20.500.12110/paper_03693554_v45_n1_p32_Blum
work_keys_str_mv AT blumlesser harmonicmodelofmolecularrearrangementcollisions
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