Infra-red absorption intensities and bond moments in BCl3
The infra-red absorption intensities of the fundamental vibration bands of BCl3 have been measured. These measurements yield the bond moment μ (BCl) = ±0·59 D for the A2″ class, and ±1·15 D or ±0·190 D for the E′ class. The "effective charge" is found to be ∂μ/∂r (BCl) = ±5·07 or 4·19 D/Å....
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1967
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_05848539_v23_n4_p767_deMandirola http://hdl.handle.net/20.500.12110/paper_05848539_v23_n4_p767_deMandirola |
| Aporte de: |
| Sumario: | The infra-red absorption intensities of the fundamental vibration bands of BCl3 have been measured. These measurements yield the bond moment μ (BCl) = ±0·59 D for the A2″ class, and ±1·15 D or ±0·190 D for the E′ class. The "effective charge" is found to be ∂μ/∂r (BCl) = ±5·07 or 4·19 D/Å. © 1967. |
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