Proton deshielding by spatial proximity: An experimental and theoretical study for ortho‐substituted anisoles
A quantitative estimation of the proton deshielding effect produced by a sterically crowded environment was obtained experimentally, based on departures from the chemical shift additivity rule of protons ortho to OCH3 and NO2 groups in benzene derivatives, where a conformational change from these si...
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Autores principales: | Contreras, Rubén Horacio, Ferraro, Marta Beatriz |
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Publicado: |
1985
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v23_n5_p296_Contreras http://hdl.handle.net/20.500.12110/paper_07491581_v23_n5_p296_Contreras |
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