Stereocontrolled synthesis of stereoregular, chiral analogs of nylon 5,5 and nylon 5,6

L-glutamic acid (1) was employed as a chiral template in the preparation of the pentachlorophenyl ester of (4S)-carboxy-1,4-butirolactone (3), a key precursor of chiral analogs of nylon 5,5 and nylon 5,6. Stereocontrol in the synthesis of these polymers was achieved by chemoselective condensation of...

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Detalles Bibliográficos
Publicado:	1997
Materias:	nylon polymer article chirality drug synthesis in vitro study nuclear magnetic resonance spectroscopy priority journal reaction analysis stereochemistry
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09574166_v8_n9_p1383_Orgueira http://hdl.handle.net/20.500.12110/paper_09574166_v8_n9_p1383_Orgueira
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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