Photophysics and Photochemistry of 22π and 26π Acetylene-Cumulene Porphyrinoids

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The aromatic 26π acetylene-cumulene porphyrinoid 8 has been synthesized by a reaction sequence involving reductive carbonyl coupling of the dialdehyde 12 utilizing low-valent titanium in the crucial step. Like its lower 22π homologs 6 and 7, the new tetrapyrrolic macrocycle 8 is centrosymmetric in t...

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Detalles Bibliográficos
Autores principales:	Mãrtire, D.O., Jux, N., Aramendía, P.F., Martín Negri, R., Lex, J., Braslavsky, S.E., Schaffner, K., Vogel, E.
Formato:	JOUR
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00027863_v114_n25_p9969_Martire
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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