HNO Is Produced by the Reaction of NO with Thiols

Azanone (nitroxyl, HNO) is a highly reactive compound whose biological role is still a matter of debate. One possible route for its formation is NO reduction by biological reductants. These reactions have been historically discarded due to the negative redox potential for the NO,H+/HNO couple. Howev...

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Detalles Bibliográficos
Autores principales: Suarez, S.A., Muñoz, M., Alvarez, L., Venâncio, M.F., Rocha, W.R., Bikiel, D.E., Marti, M.A., Doctorovich, F.
Formato: JOUR
Materias:
Aromatic compounds
Free radicals
Manganese
Molecules
Ab initio method
Anaerobic conditions
Aromatic alcohols
Aromatic thiol
Mechanistic analysis
Mn porphyrins
Potential sources
Redox potentials
Redox reactions
alpha tocopherol
ascorbic acid
azanone
hydroquinone
manganese
nitric oxide
nitroxyl
thiol derivative
tyrosine
unclassified drug
ab initio calculation
Article
chemical reaction
controlled study
density functional theory
dimerization
nuclear magnetic resonance spectroscopy
nucleophilicity
oxidation reduction potential
proton transport
rate constant
tautomer
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00027863_v139_n41_p14483_Suarez
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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