Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles

The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the c...

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Autores principales: Seldes, A.M., Gros, E.G., Thiel, I.M.E., Deferrari, J.O.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes
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spelling todo:paper_00086215_v39_n1_p11_Seldes2023-10-03T14:07:33Z Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles Seldes, A.M. Gros, E.G. Thiel, I.M.E. Deferrari, J.O. The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the carbon chain, whereas, for those having the xylo, ribo, and gluco configurations, the values of the coupling constants indicate that a bent conformation is favored. © 1975. Fil:Seldes, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Thiel, I.M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the carbon chain, whereas, for those having the xylo, ribo, and gluco configurations, the values of the coupling constants indicate that a bent conformation is favored. © 1975.
format JOUR
author Seldes, A.M.
Gros, E.G.
Thiel, I.M.E.
Deferrari, J.O.
spellingShingle Seldes, A.M.
Gros, E.G.
Thiel, I.M.E.
Deferrari, J.O.
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
author_facet Seldes, A.M.
Gros, E.G.
Thiel, I.M.E.
Deferrari, J.O.
author_sort Seldes, A.M.
title Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
title_short Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
title_full Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
title_fullStr Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
title_full_unstemmed Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
title_sort conformations of some per-o-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
url http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes
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