Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles
The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the c...
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Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes |
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todo:paper_00086215_v39_n1_p11_Seldes2023-10-03T14:07:33Z Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles Seldes, A.M. Gros, E.G. Thiel, I.M.E. Deferrari, J.O. The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the carbon chain, whereas, for those having the xylo, ribo, and gluco configurations, the values of the coupling constants indicate that a bent conformation is favored. © 1975. Fil:Seldes, A.M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Thiel, I.M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Deferrari, J.O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. JOUR info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes |
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Universidad de Buenos Aires |
institution_str |
I-28 |
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R-134 |
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The conformations of several per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles in pyridine-d5 solution have been studied by p.m.r. spectroscopy. For compounds of both types, those having the arabino, galacto, and manno configurations take an extended, planar, zigzag arrangement for the carbon chain, whereas, for those having the xylo, ribo, and gluco configurations, the values of the coupling constants indicate that a bent conformation is favored. © 1975. |
format |
JOUR |
author |
Seldes, A.M. Gros, E.G. Thiel, I.M.E. Deferrari, J.O. |
spellingShingle |
Seldes, A.M. Gros, E.G. Thiel, I.M.E. Deferrari, J.O. Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
author_facet |
Seldes, A.M. Gros, E.G. Thiel, I.M.E. Deferrari, J.O. |
author_sort |
Seldes, A.M. |
title |
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
title_short |
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
title_full |
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
title_fullStr |
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
title_full_unstemmed |
Conformations of some per-O-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
title_sort |
conformations of some per-o-acetylaldononitriles and 5-(polyacetoxyalkyl)tetrazoles |
url |
http://hdl.handle.net/20.500.12110/paper_00086215_v39_n1_p11_Seldes |
work_keys_str_mv |
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1807320571036303360 |