Methylation of carbohydrates bearing base-labile substituents, with diazomethane-boron triflouride etherate. I
Various tetra-O-acetyl-D-hexopyranoses were known to undergo acetyl migration upon methylation with Purdie's reagents; thus, 1,2,3,4-tetra-O-acetyl-β-D-glucopyranose, 1,2,3,6-tetra-O-acetyl-β-D-glucopyranose, and 1,3,4,6-tetra-O-acetyl-β-D-glucopyranose and its α anomer are converted into methy...
Autores principales: | Mastronardi, I.O., Flematti, S.M., Deferrari, J.O., Gros, E.G. |
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Formato: | JOUR |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v3_n2_p177_Mastronardi |
Aporte de: |
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