Comparative Bonding and Photophysical Properties of 2,2′-Bipyridine and 2,2′-Bipyrazine in Tetracyano Complexes Containing Ruthenium and Osmium
The (2,2′-bipyrazine)ruthenium(II)- and (2,2′-bipyridine)osmium(II)-tetracyanide complexes were prepared as sodium and potassium salts, respectively. Assignments of the MLCT (dπ(M) →- p(L-L)) and IL (π(L-L) → π(L-L)) bands were performed analyzing spectra in aqueous solution and in organic solvents....
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| Autores principales: | Posse, M.E.G., Katz, N.E., Baraldo, L.M., Polonuer, D.D., Colombano, C.G., Olabe, J.A. |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v34_n7_p1830_Posse |
| Aporte de: |
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