Electronic Structure and Substitution and Redox Reactivity of Imidazolate-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium

The mixed-valence compound [(NC)5FeII-Im-RuIII(NH3) 5]-,Mi, was prepared in solution and as a solid sodium salt from [Fe(CN)5H2O]3- and [Ru(NH3)5Im]2+. The binuclear complex shows two bands at 366 nm (∈ = 3350 M-1 cm-1) and 576 nm (∈ = 1025 M-1 cm-1), assigned as LMCT transitions, as well as a near-...

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Detalles Bibliográficos
Autores principales:	Parise, A.R., Baraldo, L.M., Olabe, J.A.
Formato:	JOUR
Acceso en línea:	http://hdl.handle.net/20.500.12110/paper_00201669_v35_n17_p5080_Parise
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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