Mixed-Valence Cyanopyridine-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium: Electronic Structure, Stability, and Redox Reactivity
The mixed-valence binuclear complexes, [(NC)5Fe(pyCN)Ru(NH3)5]n (4- and 3-cyanopyridine isomers, with nitrile-N and pyridine-N binding to Ru and Fe, respectively) were prepared as solid compounds through stoichiometric oxidation of the fully reduced (II,II) binuclear complexes, R, with peroxydisulfa...
Guardado en:
| Autores principales: | Almaraz, A.E., Gentil, L.A., Baraldo, L.M., Olabe, J.A. |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v35_n26_p7718_Almaraz |
| Aporte de: |
Ejemplares similares
-
Mixed-Valence Cyanopyridine-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium: Electronic Structure, Stability, and Redox Reactivity
Publicado: (1996) -
Electronic Structure and Substitution and Redox Reactivity of Imidazolate-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium
por: Parise, A.R., et al. -
Electronic Structure and Substitution and Redox Reactivity of Imidazolate-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium
por: Parise, Alejandro Rubén, et al.
Publicado: (1996) -
Kinetics of formation, dissociation, and isomerization reactions in complexes of cyanopyridines and benzonitrile with pentacyanoruthenate(II)
por: Almaraz, A.E., et al. -
Exploring the properties of mixed valence cyanide bridged dinuclear complexes: Solvent stabilization of electronic isomers
por: Rossi, M.B., et al.