Spectroelectrochemical Characterization of the Two-Step Redox System {(μ-pz)[Os(CN)5]2}n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System
The pyrazine-bridged diosmium(II) complex {(μ-C4H4N2)[Os(CN)5] 2}6- has been synthesized as the hexapotassium salt and was converted to the hexakis(tetrabutylammonium) compound by ion exchange. Its stepwise oxidation to the Os2IIIOsII and Os2IIIOsIII states was monitored spectroelectrochemically in...
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| Autores principales: | Hornung, F.M., Baumann, F., Kaim, W., Olabe, J.A., Slep, L.D., Fiedler, J. |
|---|---|
| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v37_n2_p311_Hornung |
| Aporte de: |
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