Kinetics and mechanism of the interaction of nitric oxide with pentacyanoferrate(II). Formation and dissociation of [Fe(CN)5NO]3-
The interaction of NO with [Fe(CN)5H2O]3- (generated by aquation of the corresponding ammine complex) to produce [Fe(CN)5NO]3- was studied by UV-vis spectrophotometry. The reaction product is the well characterized nitrosyl complex, described as a low-spin Fe(II) bound to the NO radical. The experim...
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| Autores principales: | Roncaroli, F., Olabe, J.A., Van Eldik, R. |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v42_n13_p4179_Roncaroli |
| Aporte de: |
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