Role of ruthenium oxidation states in ligand-to-ligand charge transfer processes

We describe in this paper the properties of [Ru II/III(bpy) 2ClL] +1/+2 and [Ru II/III(bpy) 2L 2] +2/+3. L = ditolyl-3-pyridylamine (dt3pya) is a redox active ligand related to triarylamines, which is very similar to 3-aminopyridine except for the reversible redox behavior. The monosubstituted compl...

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Autores principales: Ramírez, C.L., Pegoraro, C.N., Filevich, O., Bruttomeso, A., Etchenique, R., Parise, A.R.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00201669_v51_n3_p1261_Ramirez
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