Carbon-Carbon Bond Formation through the Carbonylation of Lithium Dialkylamides. One-Pot Synthesis of N-Alkyl-Substituted Formamides, Glyoxylamides, and Hydroxymalonamides

The reaction of lithium dialkylamides 1 (dialkyl = dibutyl, dipentyl, dicyclohexyl, 3-oxapentamethylene, and isopropyl cyclohexyl) with carbon monoxide was examined under several reaction conditions. It is shown that the corresponding lithium carbamoyl is the first intermediate and its further react...

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Detalles Bibliográficos
Autores principales: Pérez, D.G., Sbarbati Nudelman, N.
Formato: JOUR
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00223263_v53_n2_p408_Perez
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