Synthesis of chiral polyhydroxy polyamides having chains of defined regio and stereoregularity
1,6-Diaminohexane and a 2-(S)-hydroxypentanedioic acid 5,2-lactone derivative (3) were polycondensed to afford an aregic polyamide 4. A chiral monomer (5) having a 2-fold axis of symmetry was chemoselectively constructed from 3, and upon polymerization with the diamine led to an AABB-type polyamide...
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| Autores principales: | Orgueira, H.A., Erra-Balsells, R., Nonami, H., Varela, O. |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00249297_v34_n4_p687_Orgueira |
| Aporte de: |
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